Template-Controlled Oligomerization Support Studies. Template Synthesis and Functionalization

Ken S. Feldman, John S. Bobc, Susan M. Ensel, Yoon B. Lee, Paul H. Weinreb

Research output: Contribution to journalArticle

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Abstract

The rigid organic template 8 can be rapidly assembled via double Diels-Alder cycloaddition of methyl 9-anthracenecarboxylate (7) and trams-anti-trans-norbornadiene trimer 5. Subsequent manipulation leads to differentially functionalized templates capable of mediating the oligoselective polymerization of acrylate monomers. Lactonization studies with template diol 10 provide a useful measure of the “effective molecular size” of the template.

Original languageEnglish (US)
Pages (from-to)474-481
Number of pages8
JournalJournal of Organic Chemistry
Volume55
Issue number2
DOIs
Publication statusPublished - Jan 1 1990

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All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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