Template-controlled oligomerization. The search for bimolecular termination

Ken S. Feldman, John S. Bobo, Gregory L. Tewalt

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Bimolecular termination was probed in benzene and in methyl isobutyrate using exogenous terminator and a previously described template system effective in controlling oligoselectivity in the free-radical-mediated polymerization of methyl methacrylate. As expected, increasing amounts of added terminator led to a decrease in intramolecular termination (cyclization). However, differences in reactivity profiles with different added terminators in the two solvents are consistent with the intervention of solvent-enforced control of chain-template dynamics.

Original languageEnglish (US)
Pages (from-to)4573-4574
Number of pages2
JournalJournal of Organic Chemistry
Volume57
Issue number17
StatePublished - 1992

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Oligomerization
Isobutyrates
Methacrylates
Cyclization
Free radical polymerization
Benzene

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

Feldman, K. S., Bobo, J. S., & Tewalt, G. L. (1992). Template-controlled oligomerization. The search for bimolecular termination. Journal of Organic Chemistry, 57(17), 4573-4574.
Feldman, Ken S. ; Bobo, John S. ; Tewalt, Gregory L. / Template-controlled oligomerization. The search for bimolecular termination. In: Journal of Organic Chemistry. 1992 ; Vol. 57, No. 17. pp. 4573-4574.
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Feldman, KS, Bobo, JS & Tewalt, GL 1992, 'Template-controlled oligomerization. The search for bimolecular termination', Journal of Organic Chemistry, vol. 57, no. 17, pp. 4573-4574.

Template-controlled oligomerization. The search for bimolecular termination. / Feldman, Ken S.; Bobo, John S.; Tewalt, Gregory L.

In: Journal of Organic Chemistry, Vol. 57, No. 17, 1992, p. 4573-4574.

Research output: Contribution to journalArticle

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