Tetrabutylammonium isobutyl silsesquioxane monochloroferrate(III)

Michael Hay, Steven J. Geib

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The title compound, tetrabutylammonium chloroheptaiso-butyldodeca-μ-oxo- heptasiliconiron, [(C4H9)4N][FeSi 7ClO12-(C4H9)7], is an ionic species consisting of a tetrabutyl-ammonium cation and an isobutyl silsesquioxane monochloroferrate(III) anion. The FeIII atom in the anion is tetrahedrally coordinated by a single Cl atom and three silanoxides from the tridentate isobutyl silsesquioxane ligand, while the cation exists also in a tetrahedral arrangement.

Original languageEnglish (US)
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number2
DOIs
StatePublished - Feb 1 2007

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Anions
Cations
Negative ions
Positive ions
anions
cations
Atoms
Ammonium Compounds
atoms
Ligands
ligands
tetrabutylammonium

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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abstract = "The title compound, tetrabutylammonium chloroheptaiso-butyldodeca-μ-oxo- heptasiliconiron, [(C4H9)4N][FeSi 7ClO12-(C4H9)7], is an ionic species consisting of a tetrabutyl-ammonium cation and an isobutyl silsesquioxane monochloroferrate(III) anion. The FeIII atom in the anion is tetrahedrally coordinated by a single Cl atom and three silanoxides from the tridentate isobutyl silsesquioxane ligand, while the cation exists also in a tetrahedral arrangement.",
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Tetrabutylammonium isobutyl silsesquioxane monochloroferrate(III). / Hay, Michael; Geib, Steven J.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 2, 01.02.2007.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Tetrabutylammonium isobutyl silsesquioxane monochloroferrate(III)

AU - Hay, Michael

AU - Geib, Steven J.

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N2 - The title compound, tetrabutylammonium chloroheptaiso-butyldodeca-μ-oxo- heptasiliconiron, [(C4H9)4N][FeSi 7ClO12-(C4H9)7], is an ionic species consisting of a tetrabutyl-ammonium cation and an isobutyl silsesquioxane monochloroferrate(III) anion. The FeIII atom in the anion is tetrahedrally coordinated by a single Cl atom and three silanoxides from the tridentate isobutyl silsesquioxane ligand, while the cation exists also in a tetrahedral arrangement.

AB - The title compound, tetrabutylammonium chloroheptaiso-butyldodeca-μ-oxo- heptasiliconiron, [(C4H9)4N][FeSi 7ClO12-(C4H9)7], is an ionic species consisting of a tetrabutyl-ammonium cation and an isobutyl silsesquioxane monochloroferrate(III) anion. The FeIII atom in the anion is tetrahedrally coordinated by a single Cl atom and three silanoxides from the tridentate isobutyl silsesquioxane ligand, while the cation exists also in a tetrahedral arrangement.

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