Tetrabutylammonium isobutyl silsesquioxane monochloroferrate(III)

Michael T. Hay; Steven J. Geib

doi:10.1107/S1600536807000360

Tetrabutylammonium isobutyl silsesquioxane monochloroferrate(III)

Michael T. Hay, Steven J. Geib

Penn State Beaver

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The title compound, tetrabutylammonium chloroheptaiso-butyldodeca-μ-oxo- heptasiliconiron, [(C₄H₉)₄N][FeSi ₇ClO₁₂-(C₄H₉)₇], is an ionic species consisting of a tetrabutyl-ammonium cation and an isobutyl silsesquioxane monochloroferrate(III) anion. The Fe^III atom in the anion is tetrahedrally coordinated by a single Cl atom and three silanoxides from the tridentate isobutyl silsesquioxane ligand, while the cation exists also in a tetrahedral arrangement.

Original language	English (US)
Pages (from-to)	m445-m446
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	2
DOIs	https://doi.org/10.1107/S1600536807000360
State	Published - Feb 1 2007

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1107/S1600536807000360

Cite this

@article{443ce1aea7274877927713501a32c11c,

title = "Tetrabutylammonium isobutyl silsesquioxane monochloroferrate(III)",

abstract = "The title compound, tetrabutylammonium chloroheptaiso-butyldodeca-μ-oxo- heptasiliconiron, [(C4H9)4N][FeSi 7ClO12-(C4H9)7], is an ionic species consisting of a tetrabutyl-ammonium cation and an isobutyl silsesquioxane monochloroferrate(III) anion. The FeIII atom in the anion is tetrahedrally coordinated by a single Cl atom and three silanoxides from the tridentate isobutyl silsesquioxane ligand, while the cation exists also in a tetrahedral arrangement.",

author = "Hay, {Michael T.} and Geib, {Steven J.}",

year = "2007",

month = feb,

day = "1",

doi = "10.1107/S1600536807000360",

language = "English (US)",

volume = "63",

pages = "m445--m446",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "2",

}

TY - JOUR

T1 - Tetrabutylammonium isobutyl silsesquioxane monochloroferrate(III)

AU - Hay, Michael T.

AU - Geib, Steven J.

PY - 2007/2/1

Y1 - 2007/2/1

N2 - The title compound, tetrabutylammonium chloroheptaiso-butyldodeca-μ-oxo- heptasiliconiron, [(C4H9)4N][FeSi 7ClO12-(C4H9)7], is an ionic species consisting of a tetrabutyl-ammonium cation and an isobutyl silsesquioxane monochloroferrate(III) anion. The FeIII atom in the anion is tetrahedrally coordinated by a single Cl atom and three silanoxides from the tridentate isobutyl silsesquioxane ligand, while the cation exists also in a tetrahedral arrangement.

AB - The title compound, tetrabutylammonium chloroheptaiso-butyldodeca-μ-oxo- heptasiliconiron, [(C4H9)4N][FeSi 7ClO12-(C4H9)7], is an ionic species consisting of a tetrabutyl-ammonium cation and an isobutyl silsesquioxane monochloroferrate(III) anion. The FeIII atom in the anion is tetrahedrally coordinated by a single Cl atom and three silanoxides from the tridentate isobutyl silsesquioxane ligand, while the cation exists also in a tetrahedral arrangement.

UR - http://www.scopus.com/inward/record.url?scp=33846990538&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33846990538&partnerID=8YFLogxK

U2 - 10.1107/S1600536807000360

DO - 10.1107/S1600536807000360

M3 - Article

AN - SCOPUS:33846990538

SN - 1600-5368

VL - 63

SP - m445-m446

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 2

ER -

Tetrabutylammonium isobutyl silsesquioxane monochloroferrate(III)

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this