The adsorption of bisulfate and sulfate anions over a Pt(1 1 1) electrode: A first principle study of adsorption configurations, vibrational frequencies and linear sweep voltammogram simulations

Kuan Yu Yeh, Nicholas A. Restaino, Monica R. Esopi, Janna Kay Maranas, Michael John Janik

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34 Citations (Scopus)

Abstract

Specific anion adsorption of sulfate and bisulfate anions to the Pt(1 1 1) surface was studied using periodic density functional theory (DFT) methods. The origins of experimentally observed voltammetric features have been assigned based on comparison of calculated vibrational frequencies and simulated linear sweep voltammograms (LSVs) to experimental data available in the literature. The inclusion of solvation in the electrochemical model well-predicts the bisulfate and sulfate adsorption potentials. Combined with vibrational frequency analysis, sulfate is identified as the dominant adsorption species over the (bi)sulfate adsorption potential region. Rapid increase of coverage with electrode potential causes a sharp peak in the simulated voltammogram. We have assigned the experimental characteristic vibrational mode of adsorbed (bi)sulfate in the 1200-1300 cm-1 range as an S-O uncoordinated stretch. The Stark tuning slope of the S-O uncoordinated frequency for sulfate containing (√3 × √7) superstructures was calculated for different co-adsorbed species to resolve possible molecular structures for this adlayer. The oxidation of co-adsorbed water to surface hydroxyl at (√3 × √7) adlayer causes a decrease of the Stark tuning slope and a high potential feature in the voltammogram. The adsorption of a series of sulfonic acids to Pt(1 1 1) is considered, and the calculated adsorption equilibrium potential is observed to correlate linearly with the sulfonate proton affinity.

Original languageEnglish (US)
Pages (from-to)20-35
Number of pages16
JournalCatalysis Today
Volume202
Issue number1
DOIs
StatePublished - Mar 15 2013

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Vibrational spectra
Sulfates
Anions
Negative ions
Adsorption
Electrodes
Tuning
Sulfonic Acids
Solvation
Hydroxyl Radical
Molecular structure
Density functional theory
Protons
Oxidation
Acids
Water

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

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abstract = "Specific anion adsorption of sulfate and bisulfate anions to the Pt(1 1 1) surface was studied using periodic density functional theory (DFT) methods. The origins of experimentally observed voltammetric features have been assigned based on comparison of calculated vibrational frequencies and simulated linear sweep voltammograms (LSVs) to experimental data available in the literature. The inclusion of solvation in the electrochemical model well-predicts the bisulfate and sulfate adsorption potentials. Combined with vibrational frequency analysis, sulfate is identified as the dominant adsorption species over the (bi)sulfate adsorption potential region. Rapid increase of coverage with electrode potential causes a sharp peak in the simulated voltammogram. We have assigned the experimental characteristic vibrational mode of adsorbed (bi)sulfate in the 1200-1300 cm-1 range as an S-O uncoordinated stretch. The Stark tuning slope of the S-O uncoordinated frequency for sulfate containing (√3 × √7) superstructures was calculated for different co-adsorbed species to resolve possible molecular structures for this adlayer. The oxidation of co-adsorbed water to surface hydroxyl at (√3 × √7) adlayer causes a decrease of the Stark tuning slope and a high potential feature in the voltammogram. The adsorption of a series of sulfonic acids to Pt(1 1 1) is considered, and the calculated adsorption equilibrium potential is observed to correlate linearly with the sulfonate proton affinity.",
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AU - Restaino, Nicholas A.

AU - Esopi, Monica R.

AU - Maranas, Janna Kay

AU - Janik, Michael John

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AB - Specific anion adsorption of sulfate and bisulfate anions to the Pt(1 1 1) surface was studied using periodic density functional theory (DFT) methods. The origins of experimentally observed voltammetric features have been assigned based on comparison of calculated vibrational frequencies and simulated linear sweep voltammograms (LSVs) to experimental data available in the literature. The inclusion of solvation in the electrochemical model well-predicts the bisulfate and sulfate adsorption potentials. Combined with vibrational frequency analysis, sulfate is identified as the dominant adsorption species over the (bi)sulfate adsorption potential region. Rapid increase of coverage with electrode potential causes a sharp peak in the simulated voltammogram. We have assigned the experimental characteristic vibrational mode of adsorbed (bi)sulfate in the 1200-1300 cm-1 range as an S-O uncoordinated stretch. The Stark tuning slope of the S-O uncoordinated frequency for sulfate containing (√3 × √7) superstructures was calculated for different co-adsorbed species to resolve possible molecular structures for this adlayer. The oxidation of co-adsorbed water to surface hydroxyl at (√3 × √7) adlayer causes a decrease of the Stark tuning slope and a high potential feature in the voltammogram. The adsorption of a series of sulfonic acids to Pt(1 1 1) is considered, and the calculated adsorption equilibrium potential is observed to correlate linearly with the sulfonate proton affinity.

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