The basic hydrolysis of hexakis(aryloxy)cyclotriphosphazenes

H. R. Allcock, E. J. Walsh

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Kinetic and product analysis studies of the alkaline hydrolysis of hexakis(aryloxy)cyclotriphosphazenes in 25 vol.% aqueous diglyme revealed an SN2-type mechanism for cleavage of the first aryloxy-side-group from phosphorus: the hydrolysis rate was considerably enhanced by 2- or 4-nitro-groups and retarded by 4-methyl groups in the aryl ring.

Original languageEnglish (US)
Pages (from-to)580a-580a
JournalJournal of the Chemical Society D: Chemical Communications
Issue number10
DOIs
StatePublished - Dec 1 1970

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Hydrolysis
Phosphorus
Kinetics
diglyme

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

Cite this

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The basic hydrolysis of hexakis(aryloxy)cyclotriphosphazenes. / Allcock, H. R.; Walsh, E. J.

In: Journal of the Chemical Society D: Chemical Communications, No. 10, 01.12.1970, p. 580a-580a.

Research output: Contribution to journalArticle

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