The effects of diagenesis and dolomitization on Ca and Mg isotopes in marine platform carbonates: Implications for the geochemical cycles of Ca and Mg

Matthew S. Fantle, John Higgins

Research output: Contribution to journalArticle

64 Citations (Scopus)

Abstract

The Ca, Mg, O, and C isotopic and trace elemental compositions of marine limestones and dolostones from ODP Site 1196A, which range in depth (~58 to 627. mbsf) and in depositional age (~5 and 23. Ma), are presented. The objectives of the study are to explore the potential for non-traditional isotope systems to fingerprint diagenesis, to quantify the extent to which geochemical proxies are altered during diagenesis, and to investigate the importance of diagenesis within the global Ca and Mg geochemical cycles. The data suggest that Ca, which has a relatively high solid to fluid mass ratio, can be isotopically altered during diagenesis. In addition, the alteration of Ca correlates with the alteration of Mg in such a way that both can serve as useful tools for deciphering diagenesis in ancient rocks.Bulk carbonate δ44Ca values vary between 0.60 and 1.31‰ (SRM-915a scale); the average limestone δ44Ca is 0.97±0.24‰ (1SD), identical within error to the average dolostone (1.03±0.15 1SD ‰). Magnesium isotopic compositions (δ26Mg, DSM-3 scale) range between -2.59‰ and -3.91‰, and limestones (-3.60±0.25‰) and dolostones (-2.68±0.07‰) are isotopically distinct. Carbon isotopic compositions (δ13C, PDB scale) vary between 0.86‰ and 2.47‰, with average limestone (1.96±0.31‰) marginally offset relative to average dolostone (1.68±0.57‰). The oxygen isotopic compositions (δ18O, PDB scale) of limestones (-1.22±0.94‰) are substantially lower than the dolostones measured (2.72±1.07‰).The isotopic data from 1196A suggest distinct and coherent trends in isotopic and elemental compositions that are interpreted in terms of diagenetic trajectories. Numerical modeling supports the contention that such trends can be interpreted as diagenetic, and suggests that the appropriate distribution coefficient (KMg) associated with limestone diagenesis is ~1 to 5×10-3, distinctly lower than those values (>0.015) reported in laboratory studies. With respect to Mg isotopes, the modeling also suggest that diagenetic fractionation factors of ~0.9955 (-4.5‰) and 0.9980 (-2‰) are appropriate for limestone diagenesis and dolomitization, respectively.

Original languageEnglish (US)
Pages (from-to)458-481
Number of pages24
JournalGeochimica et Cosmochimica Acta
Volume142
DOIs
StatePublished - Oct 1 2014

Fingerprint

geochemical cycle
Ocean structures
Calcium Carbonate
dolomitization
Carbonates
carbonate platform
Isotopes
diagenesis
dolostone
limestone
isotope
Chemical analysis
isotopic composition
Fractionation
effect
Ocean Drilling Program
Magnesium
modeling
magnesium
Carbon

All Science Journal Classification (ASJC) codes

  • Geochemistry and Petrology

Cite this

@article{0b7477ca2e864bbd8b9ac6cffaf08410,
title = "The effects of diagenesis and dolomitization on Ca and Mg isotopes in marine platform carbonates: Implications for the geochemical cycles of Ca and Mg",
abstract = "The Ca, Mg, O, and C isotopic and trace elemental compositions of marine limestones and dolostones from ODP Site 1196A, which range in depth (~58 to 627. mbsf) and in depositional age (~5 and 23. Ma), are presented. The objectives of the study are to explore the potential for non-traditional isotope systems to fingerprint diagenesis, to quantify the extent to which geochemical proxies are altered during diagenesis, and to investigate the importance of diagenesis within the global Ca and Mg geochemical cycles. The data suggest that Ca, which has a relatively high solid to fluid mass ratio, can be isotopically altered during diagenesis. In addition, the alteration of Ca correlates with the alteration of Mg in such a way that both can serve as useful tools for deciphering diagenesis in ancient rocks.Bulk carbonate δ44Ca values vary between 0.60 and 1.31‰ (SRM-915a scale); the average limestone δ44Ca is 0.97±0.24‰ (1SD), identical within error to the average dolostone (1.03±0.15 1SD ‰). Magnesium isotopic compositions (δ26Mg, DSM-3 scale) range between -2.59‰ and -3.91‰, and limestones (-3.60±0.25‰) and dolostones (-2.68±0.07‰) are isotopically distinct. Carbon isotopic compositions (δ13C, PDB scale) vary between 0.86‰ and 2.47‰, with average limestone (1.96±0.31‰) marginally offset relative to average dolostone (1.68±0.57‰). The oxygen isotopic compositions (δ18O, PDB scale) of limestones (-1.22±0.94‰) are substantially lower than the dolostones measured (2.72±1.07‰).The isotopic data from 1196A suggest distinct and coherent trends in isotopic and elemental compositions that are interpreted in terms of diagenetic trajectories. Numerical modeling supports the contention that such trends can be interpreted as diagenetic, and suggests that the appropriate distribution coefficient (KMg) associated with limestone diagenesis is ~1 to 5×10-3, distinctly lower than those values (>0.015) reported in laboratory studies. With respect to Mg isotopes, the modeling also suggest that diagenetic fractionation factors of ~0.9955 (-4.5‰) and 0.9980 (-2‰) are appropriate for limestone diagenesis and dolomitization, respectively.",
author = "Fantle, {Matthew S.} and John Higgins",
year = "2014",
month = "10",
day = "1",
doi = "10.1016/j.gca.2014.07.025",
language = "English (US)",
volume = "142",
pages = "458--481",
journal = "Geochmica et Cosmochimica Acta",
issn = "0016-7037",
publisher = "Elsevier Limited",

}

TY - JOUR

T1 - The effects of diagenesis and dolomitization on Ca and Mg isotopes in marine platform carbonates

T2 - Implications for the geochemical cycles of Ca and Mg

AU - Fantle, Matthew S.

AU - Higgins, John

PY - 2014/10/1

Y1 - 2014/10/1

N2 - The Ca, Mg, O, and C isotopic and trace elemental compositions of marine limestones and dolostones from ODP Site 1196A, which range in depth (~58 to 627. mbsf) and in depositional age (~5 and 23. Ma), are presented. The objectives of the study are to explore the potential for non-traditional isotope systems to fingerprint diagenesis, to quantify the extent to which geochemical proxies are altered during diagenesis, and to investigate the importance of diagenesis within the global Ca and Mg geochemical cycles. The data suggest that Ca, which has a relatively high solid to fluid mass ratio, can be isotopically altered during diagenesis. In addition, the alteration of Ca correlates with the alteration of Mg in such a way that both can serve as useful tools for deciphering diagenesis in ancient rocks.Bulk carbonate δ44Ca values vary between 0.60 and 1.31‰ (SRM-915a scale); the average limestone δ44Ca is 0.97±0.24‰ (1SD), identical within error to the average dolostone (1.03±0.15 1SD ‰). Magnesium isotopic compositions (δ26Mg, DSM-3 scale) range between -2.59‰ and -3.91‰, and limestones (-3.60±0.25‰) and dolostones (-2.68±0.07‰) are isotopically distinct. Carbon isotopic compositions (δ13C, PDB scale) vary between 0.86‰ and 2.47‰, with average limestone (1.96±0.31‰) marginally offset relative to average dolostone (1.68±0.57‰). The oxygen isotopic compositions (δ18O, PDB scale) of limestones (-1.22±0.94‰) are substantially lower than the dolostones measured (2.72±1.07‰).The isotopic data from 1196A suggest distinct and coherent trends in isotopic and elemental compositions that are interpreted in terms of diagenetic trajectories. Numerical modeling supports the contention that such trends can be interpreted as diagenetic, and suggests that the appropriate distribution coefficient (KMg) associated with limestone diagenesis is ~1 to 5×10-3, distinctly lower than those values (>0.015) reported in laboratory studies. With respect to Mg isotopes, the modeling also suggest that diagenetic fractionation factors of ~0.9955 (-4.5‰) and 0.9980 (-2‰) are appropriate for limestone diagenesis and dolomitization, respectively.

AB - The Ca, Mg, O, and C isotopic and trace elemental compositions of marine limestones and dolostones from ODP Site 1196A, which range in depth (~58 to 627. mbsf) and in depositional age (~5 and 23. Ma), are presented. The objectives of the study are to explore the potential for non-traditional isotope systems to fingerprint diagenesis, to quantify the extent to which geochemical proxies are altered during diagenesis, and to investigate the importance of diagenesis within the global Ca and Mg geochemical cycles. The data suggest that Ca, which has a relatively high solid to fluid mass ratio, can be isotopically altered during diagenesis. In addition, the alteration of Ca correlates with the alteration of Mg in such a way that both can serve as useful tools for deciphering diagenesis in ancient rocks.Bulk carbonate δ44Ca values vary between 0.60 and 1.31‰ (SRM-915a scale); the average limestone δ44Ca is 0.97±0.24‰ (1SD), identical within error to the average dolostone (1.03±0.15 1SD ‰). Magnesium isotopic compositions (δ26Mg, DSM-3 scale) range between -2.59‰ and -3.91‰, and limestones (-3.60±0.25‰) and dolostones (-2.68±0.07‰) are isotopically distinct. Carbon isotopic compositions (δ13C, PDB scale) vary between 0.86‰ and 2.47‰, with average limestone (1.96±0.31‰) marginally offset relative to average dolostone (1.68±0.57‰). The oxygen isotopic compositions (δ18O, PDB scale) of limestones (-1.22±0.94‰) are substantially lower than the dolostones measured (2.72±1.07‰).The isotopic data from 1196A suggest distinct and coherent trends in isotopic and elemental compositions that are interpreted in terms of diagenetic trajectories. Numerical modeling supports the contention that such trends can be interpreted as diagenetic, and suggests that the appropriate distribution coefficient (KMg) associated with limestone diagenesis is ~1 to 5×10-3, distinctly lower than those values (>0.015) reported in laboratory studies. With respect to Mg isotopes, the modeling also suggest that diagenetic fractionation factors of ~0.9955 (-4.5‰) and 0.9980 (-2‰) are appropriate for limestone diagenesis and dolomitization, respectively.

UR - http://www.scopus.com/inward/record.url?scp=84908049470&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84908049470&partnerID=8YFLogxK

U2 - 10.1016/j.gca.2014.07.025

DO - 10.1016/j.gca.2014.07.025

M3 - Article

AN - SCOPUS:84908049470

VL - 142

SP - 458

EP - 481

JO - Geochmica et Cosmochimica Acta

JF - Geochmica et Cosmochimica Acta

SN - 0016-7037

ER -