The effects of phosphorus compounds on PAH and soot across a suite of laboratory devices

S. Sidhu, V. Belovich, M. Colket, M. Kahandawala, V. Katta, D. Liscinsky, Thomas Litzinger, K. McNesby, R. Pawlik, M. Roquemore, R. Santoro, S. Stouffer

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Recently researchers from universities, industry and governmental laboratories completed a collaborative study that investigated the impact of different types of organic fuel additives on soot and PAH emissions from military gas turbine engines. The main objective of this program was to obtain fundamental understanding of how even a small changes in fuel composition can affect soot and PAH emissions. Six different combustors namely, a premixed flame, a co-flow diffusion flame, an opposed-flow diffusion flame, a well-stirred reactor, a shock tube, and a swirl-stablized combustor were used to investigate the impact of additives covering a wide range of combustion conditions. The experimental results from this study were then modeled using variety modeling packages and mechanisms. This paper will summarize the key results from studies of the effects of phosphorus additives, trimethyl phosphite, trimethyl phosphate, diethyl allyl phosphate, and dimethyl methyl phosphonate on soot and PAH for several gaseous fuels and a simple JP8 surrogate, heptane/toluene.

Original languageEnglish (US)
Title of host publication5th US Combustion Meeting 2007
PublisherCombustion Institute
Pages2589-2605
Number of pages17
ISBN (Electronic)9781604238112
StatePublished - Jan 1 2007
Event5th US Combustion Meeting 2007 - San Diego, United States
Duration: Mar 25 2007Mar 28 2007

Publication series

Name5th US Combustion Meeting 2007
Volume4

Other

Other5th US Combustion Meeting 2007
CountryUnited States
CitySan Diego
Period3/25/073/28/07

Fingerprint

Phosphorus Compounds
Phosphorus compounds
phosphorus compounds
Soot
soot
polycyclic aromatic hydrocarbons
Polycyclic aromatic hydrocarbons
trimethyl phosphite
diffusion flames
combustion chambers
Combustors
phosphates
Phosphates
gaseous fuels
Fuel additives
gas turbine engines
Heptanes
Organophosphonates
Shock tubes
premixed flames

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Physical and Theoretical Chemistry
  • Mechanical Engineering

Cite this

Sidhu, S., Belovich, V., Colket, M., Kahandawala, M., Katta, V., Liscinsky, D., ... Stouffer, S. (2007). The effects of phosphorus compounds on PAH and soot across a suite of laboratory devices. In 5th US Combustion Meeting 2007 (pp. 2589-2605). (5th US Combustion Meeting 2007; Vol. 4). Combustion Institute.
Sidhu, S. ; Belovich, V. ; Colket, M. ; Kahandawala, M. ; Katta, V. ; Liscinsky, D. ; Litzinger, Thomas ; McNesby, K. ; Pawlik, R. ; Roquemore, M. ; Santoro, R. ; Stouffer, S. / The effects of phosphorus compounds on PAH and soot across a suite of laboratory devices. 5th US Combustion Meeting 2007. Combustion Institute, 2007. pp. 2589-2605 (5th US Combustion Meeting 2007).
@inproceedings{9dec802a2c7f4e469fe8800537112db8,
title = "The effects of phosphorus compounds on PAH and soot across a suite of laboratory devices",
abstract = "Recently researchers from universities, industry and governmental laboratories completed a collaborative study that investigated the impact of different types of organic fuel additives on soot and PAH emissions from military gas turbine engines. The main objective of this program was to obtain fundamental understanding of how even a small changes in fuel composition can affect soot and PAH emissions. Six different combustors namely, a premixed flame, a co-flow diffusion flame, an opposed-flow diffusion flame, a well-stirred reactor, a shock tube, and a swirl-stablized combustor were used to investigate the impact of additives covering a wide range of combustion conditions. The experimental results from this study were then modeled using variety modeling packages and mechanisms. This paper will summarize the key results from studies of the effects of phosphorus additives, trimethyl phosphite, trimethyl phosphate, diethyl allyl phosphate, and dimethyl methyl phosphonate on soot and PAH for several gaseous fuels and a simple JP8 surrogate, heptane/toluene.",
author = "S. Sidhu and V. Belovich and M. Colket and M. Kahandawala and V. Katta and D. Liscinsky and Thomas Litzinger and K. McNesby and R. Pawlik and M. Roquemore and R. Santoro and S. Stouffer",
year = "2007",
month = "1",
day = "1",
language = "English (US)",
series = "5th US Combustion Meeting 2007",
publisher = "Combustion Institute",
pages = "2589--2605",
booktitle = "5th US Combustion Meeting 2007",

}

Sidhu, S, Belovich, V, Colket, M, Kahandawala, M, Katta, V, Liscinsky, D, Litzinger, T, McNesby, K, Pawlik, R, Roquemore, M, Santoro, R & Stouffer, S 2007, The effects of phosphorus compounds on PAH and soot across a suite of laboratory devices. in 5th US Combustion Meeting 2007. 5th US Combustion Meeting 2007, vol. 4, Combustion Institute, pp. 2589-2605, 5th US Combustion Meeting 2007, San Diego, United States, 3/25/07.

The effects of phosphorus compounds on PAH and soot across a suite of laboratory devices. / Sidhu, S.; Belovich, V.; Colket, M.; Kahandawala, M.; Katta, V.; Liscinsky, D.; Litzinger, Thomas; McNesby, K.; Pawlik, R.; Roquemore, M.; Santoro, R.; Stouffer, S.

5th US Combustion Meeting 2007. Combustion Institute, 2007. p. 2589-2605 (5th US Combustion Meeting 2007; Vol. 4).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

TY - GEN

T1 - The effects of phosphorus compounds on PAH and soot across a suite of laboratory devices

AU - Sidhu, S.

AU - Belovich, V.

AU - Colket, M.

AU - Kahandawala, M.

AU - Katta, V.

AU - Liscinsky, D.

AU - Litzinger, Thomas

AU - McNesby, K.

AU - Pawlik, R.

AU - Roquemore, M.

AU - Santoro, R.

AU - Stouffer, S.

PY - 2007/1/1

Y1 - 2007/1/1

N2 - Recently researchers from universities, industry and governmental laboratories completed a collaborative study that investigated the impact of different types of organic fuel additives on soot and PAH emissions from military gas turbine engines. The main objective of this program was to obtain fundamental understanding of how even a small changes in fuel composition can affect soot and PAH emissions. Six different combustors namely, a premixed flame, a co-flow diffusion flame, an opposed-flow diffusion flame, a well-stirred reactor, a shock tube, and a swirl-stablized combustor were used to investigate the impact of additives covering a wide range of combustion conditions. The experimental results from this study were then modeled using variety modeling packages and mechanisms. This paper will summarize the key results from studies of the effects of phosphorus additives, trimethyl phosphite, trimethyl phosphate, diethyl allyl phosphate, and dimethyl methyl phosphonate on soot and PAH for several gaseous fuels and a simple JP8 surrogate, heptane/toluene.

AB - Recently researchers from universities, industry and governmental laboratories completed a collaborative study that investigated the impact of different types of organic fuel additives on soot and PAH emissions from military gas turbine engines. The main objective of this program was to obtain fundamental understanding of how even a small changes in fuel composition can affect soot and PAH emissions. Six different combustors namely, a premixed flame, a co-flow diffusion flame, an opposed-flow diffusion flame, a well-stirred reactor, a shock tube, and a swirl-stablized combustor were used to investigate the impact of additives covering a wide range of combustion conditions. The experimental results from this study were then modeled using variety modeling packages and mechanisms. This paper will summarize the key results from studies of the effects of phosphorus additives, trimethyl phosphite, trimethyl phosphate, diethyl allyl phosphate, and dimethyl methyl phosphonate on soot and PAH for several gaseous fuels and a simple JP8 surrogate, heptane/toluene.

UR - http://www.scopus.com/inward/record.url?scp=84943531828&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84943531828&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:84943531828

T3 - 5th US Combustion Meeting 2007

SP - 2589

EP - 2605

BT - 5th US Combustion Meeting 2007

PB - Combustion Institute

ER -

Sidhu S, Belovich V, Colket M, Kahandawala M, Katta V, Liscinsky D et al. The effects of phosphorus compounds on PAH and soot across a suite of laboratory devices. In 5th US Combustion Meeting 2007. Combustion Institute. 2007. p. 2589-2605. (5th US Combustion Meeting 2007).