The fate of wastewater-derived nitrate in the subsurface of the Florida Keys

Key Colony Beach, Florida

Erin M. Griggs, Lee Kump, J. K. Böhlke

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Shallow injection is the predominant mode of wastewater disposal for most tourist-oriented facilities and some residential communities in the US Florida Keys National Marine Sanctuary. Concern has been expressed that wastewater nutrients may be escaping from the saline groundwater system into canals and surrounding coastal waters and perhaps to the reef tract 10 km offshore, promoting unwanted algal growth and degradation of water quality. We performed a field study of the fate of wastewater-derived nitrate in the subsurface of a Florida Keys residential community (Key Colony Beach, FL) that uses this disposal method, analyzing samples from 21 monitoring wells and two canal sites. The results indicate that wastewater injection at 18-27 m depth into saline groundwater creates a large buoyant plume that flows quickly (within days) upward to a confining layer 6 m below the surface, and then in a fast flow path toward a canal 200 m to the east within a period of weeks to months. Low-salinity groundwaters along the fast flow path have nitrate concentrations that are not significantly reduced from that of the injected wastewaters (ranging from 400 to 600 μmolkg-1). Portions of the low-salinity plume off the main axis of flow have relatively long residence times (>2 months) and have had their nitrate concentrations strongly reduced by a combination of mixing and denitrification. These waters have dissolved N 2 concentrations up to 1.6 times air-saturation values with δ15N[N2] = 0.5 - 5‰, δ 15N[NO3 -] = 16-26‰, and calculated isotope fractionation factors of about -12±4‰, consistent with denitrification as the predominant nitrate reduction reaction. Estimated rates of denitrification of wastewater in the aquifer are of the order of 4 μmolkg-1N day-1 or 0.008 day-1. The data indicate that denitrification reduces the nitrate load of the injected wastewater substantially, but not completely, before it discharges to nearby canals.

Original languageEnglish (US)
Pages (from-to)517-539
Number of pages23
JournalEstuarine, Coastal and Shelf Science
Volume58
Issue number3
DOIs
StatePublished - Jan 1 2003

Fingerprint

beaches
wastewater
beach
nitrates
nitrate
canals (waterways)
denitrification
canal
groundwater
plume
salinity
injection
isotope fractionation
nitrate reduction
tourists
aquifers
coastal water
residence time
reefs
reef

All Science Journal Classification (ASJC) codes

  • Oceanography
  • Aquatic Science

Cite this

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title = "The fate of wastewater-derived nitrate in the subsurface of the Florida Keys: Key Colony Beach, Florida",
abstract = "Shallow injection is the predominant mode of wastewater disposal for most tourist-oriented facilities and some residential communities in the US Florida Keys National Marine Sanctuary. Concern has been expressed that wastewater nutrients may be escaping from the saline groundwater system into canals and surrounding coastal waters and perhaps to the reef tract 10 km offshore, promoting unwanted algal growth and degradation of water quality. We performed a field study of the fate of wastewater-derived nitrate in the subsurface of a Florida Keys residential community (Key Colony Beach, FL) that uses this disposal method, analyzing samples from 21 monitoring wells and two canal sites. The results indicate that wastewater injection at 18-27 m depth into saline groundwater creates a large buoyant plume that flows quickly (within days) upward to a confining layer 6 m below the surface, and then in a fast flow path toward a canal 200 m to the east within a period of weeks to months. Low-salinity groundwaters along the fast flow path have nitrate concentrations that are not significantly reduced from that of the injected wastewaters (ranging from 400 to 600 μmolkg-1). Portions of the low-salinity plume off the main axis of flow have relatively long residence times (>2 months) and have had their nitrate concentrations strongly reduced by a combination of mixing and denitrification. These waters have dissolved N 2 concentrations up to 1.6 times air-saturation values with δ15N[N2] = 0.5 - 5‰, δ 15N[NO3 -] = 16-26‰, and calculated isotope fractionation factors of about -12±4‰, consistent with denitrification as the predominant nitrate reduction reaction. Estimated rates of denitrification of wastewater in the aquifer are of the order of 4 μmolkg-1N day-1 or 0.008 day-1. The data indicate that denitrification reduces the nitrate load of the injected wastewater substantially, but not completely, before it discharges to nearby canals.",
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The fate of wastewater-derived nitrate in the subsurface of the Florida Keys : Key Colony Beach, Florida. / Griggs, Erin M.; Kump, Lee; Böhlke, J. K.

In: Estuarine, Coastal and Shelf Science, Vol. 58, No. 3, 01.01.2003, p. 517-539.

Research output: Contribution to journalArticle

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