The influence of carbon nanotubes characteristics in their performance as positive electrodes in vanadium redox flow batteries

Zoraida González, Patricia Álvarez, Clara Blanco, Sofía Vega-Díaz, Ferdinando Tristán-López, Lakshmy Pulickal Rajukumar, Rodolfo Cruz-Silva, Ana Laura Elías, Mauricio Terrones, Rosa Menéndez

Research output: Contribution to journalArticle

18 Scopus citations

Abstract

Three types of multi-walled carbon nanotubes are investigated as electrodes in the positive half-cell of a vanadium redox flow battery (VRFB). Pure (MWCNTs), nitrogen-doped (CNxMWNTs) and oxygen functionalized (MWCNT-Cs) carbon nanotubes exhibit significant structural differences at the nanoscale, as well as different chemical and physical properties. The influence of such different characteristics on the electrochemical behavior towards the VO2+/VO2+ redox reactions is investigated by cyclic voltammetry, electrochemical impedance spectroscopy and charge/discharge experiments. MWCNT-Cs exhibit the best performance despite not having the largest specific surface area, neither the greatest amount of oxygen nor nitrogen functional groups on their surface. Therefore, their enhanced performance in terms of electrochemical activity and kinetic reversibility towards the vanadium reactions and energy efficiency of the corresponding static battery, are attributed to the highest sp2 carbon content, which brings the highest electrical conductivity. These results represent a significant advance in the fundamental understanding and design of effective electrode materials that will lead to more efficient batteries.

Original languageEnglish (US)
Pages (from-to)105-110
Number of pages6
JournalSustainable Energy Technologies and Assessments
Volume9
DOIs
StatePublished - Mar 1 2015

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology

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