The novel acid catalysts - Framework zirconium phosphates: The bulk and surface structure

S. N. Pavlova, V. A. Sadykov, G. V. Zabolotnaya, D. I. Kochubey, R. I. Maximovskaya, V. I. Zaikovskii, V. V. Kriventsov, S. V. Tsybulya, E. B. Burgina, A. M. Volodin, M. V. Chaikina, N. N. Kuznetsova, V. V. Lunin, D. Agrawal, R. Roy

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Abstract

Structural features and surface properties of framework zirconium phosphates synthesized via mechanochemical activation (MA) and sol-gel (SG) route were studied using XRD, TEM, 31P MAS NMR, IR and ESR spectroscopy and compared with their catalytic performance in the reaction of hexane isomerization. A high initial isomerization activity of crystalline zirconium phosphates prepared via MA can be determined by a larger share of the strong Lewis centers probed by TEMPON test molecule. (C) 2000 Elsevier Science B.V.

Original languageEnglish (US)
Pages (from-to)319-323
Number of pages5
JournalJournal of Molecular Catalysis A: Chemical
Volume158
Issue number1
DOIs
StatePublished - Sep 8 2000

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Process Chemistry and Technology
  • Physical and Theoretical Chemistry

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    Pavlova, S. N., Sadykov, V. A., Zabolotnaya, G. V., Kochubey, D. I., Maximovskaya, R. I., Zaikovskii, V. I., Kriventsov, V. V., Tsybulya, S. V., Burgina, E. B., Volodin, A. M., Chaikina, M. V., Kuznetsova, N. N., Lunin, V. V., Agrawal, D., & Roy, R. (2000). The novel acid catalysts - Framework zirconium phosphates: The bulk and surface structure. Journal of Molecular Catalysis A: Chemical, 158(1), 319-323. https://doi.org/10.1016/S1381-1169(00)00098-4