The synthesis and characterizations of monodisperse cross-linked polymer microspheres with carboxyl on the surface

Xin Chen, Zhanchen Cui, Zhimin Chen, Kai Zhang, Guang Lu, Gang Zhang, Bai Yang

Research output: Contribution to journalArticle

70 Citations (Scopus)

Abstract

Monodisperse cross-linked polymer microspheres with carboxyl groups on their surface were prepared by means of emulsifier-free emulsion copolymerization. The characterizations by X-ray photoelectron spectroscopy and conductometric titration indicate that most carboxyl groups are located on the surface of microspheres. Their swelling degree or cross-linking degree has been investigated by an in situ swelling method. Moreover, these microspheres can be easily and quickly self-organized into two- or three-dimensional ordered multilayer films or latex crystals.

Original languageEnglish (US)
Pages (from-to)4147-4152
Number of pages6
JournalPolymer
Volume43
Issue number15
DOIs
StatePublished - May 23 2002

Fingerprint

Microspheres
Polymers
Swelling
Multilayer films
Latex
Emulsions
Latexes
Titration
Copolymerization
X ray photoelectron spectroscopy
Crystals

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

Cite this

Chen, Xin ; Cui, Zhanchen ; Chen, Zhimin ; Zhang, Kai ; Lu, Guang ; Zhang, Gang ; Yang, Bai. / The synthesis and characterizations of monodisperse cross-linked polymer microspheres with carboxyl on the surface. In: Polymer. 2002 ; Vol. 43, No. 15. pp. 4147-4152.
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The synthesis and characterizations of monodisperse cross-linked polymer microspheres with carboxyl on the surface. / Chen, Xin; Cui, Zhanchen; Chen, Zhimin; Zhang, Kai; Lu, Guang; Zhang, Gang; Yang, Bai.

In: Polymer, Vol. 43, No. 15, 23.05.2002, p. 4147-4152.

Research output: Contribution to journalArticle

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AU - Chen, Xin

AU - Cui, Zhanchen

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AU - Zhang, Kai

AU - Lu, Guang

AU - Zhang, Gang

AU - Yang, Bai

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