Theory of Linear and Nonlinear Surface-Enhanced Vibrational Spectroscopies

Dhabih V. Chulhai; Zhongwei Hu; Justin E. Moore; Xing Chen; Lasse Jensen

doi:10.1146/annurev-physchem-040215-112347

Theory of Linear and Nonlinear Surface-Enhanced Vibrational Spectroscopies

Dhabih V. Chulhai, Zhongwei Hu, Justin E. Moore, Xing Chen, Lasse Jensen

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

The vibrational spectroscopy of molecules adsorbed on metal nanoparticles can be enhanced by many orders of magnitude so that the detection and identification of single molecules are possible. The enhancement of most linear and nonlinear vibrational spectroscopies has been demonstrated. In this review, we discuss theoretical approaches to understanding linear and nonlinear surface-enhanced vibrational spectroscopies. A unified description of enhancement mechanisms classified as either electromagnetic or chemical in nature is presented. Emphasis is placed on understanding the spectral changes necessary for interpretation of linear and nonlinear surface-enhanced vibrational spectroscopies.

Original language	English (US)
Pages (from-to)	541-564
Number of pages	24
Journal	Annual Review of Physical Chemistry
Volume	67
DOIs	https://doi.org/10.1146/annurev-physchem-040215-112347
State	Published - May 27 2016

All Science Journal Classification (ASJC) codes

Medicine(all)

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10.1146/annurev-physchem-040215-112347

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title = "Theory of Linear and Nonlinear Surface-Enhanced Vibrational Spectroscopies",

abstract = "The vibrational spectroscopy of molecules adsorbed on metal nanoparticles can be enhanced by many orders of magnitude so that the detection and identification of single molecules are possible. The enhancement of most linear and nonlinear vibrational spectroscopies has been demonstrated. In this review, we discuss theoretical approaches to understanding linear and nonlinear surface-enhanced vibrational spectroscopies. A unified description of enhancement mechanisms classified as either electromagnetic or chemical in nature is presented. Emphasis is placed on understanding the spectral changes necessary for interpretation of linear and nonlinear surface-enhanced vibrational spectroscopies.",

author = "Chulhai, {Dhabih V.} and Zhongwei Hu and Moore, {Justin E.} and Xing Chen and Lasse Jensen",

note = "Funding Information: We appreciate the generous support of the US National Science Foundation (NSF-CHE- 1266032) and of the UK Engineering and Physical Sciences Research Council (EP/K032062/1). We are grateful to Gilbert Nathanson, Duncan Bruce, John Slattery, George Schatz, Brooks Marshall, Simon Purcell, and Matthew Costen for many helpful discussions Publisher Copyright: Copyright {\textcopyright} 2016 by Annual Reviews. All rights reserved.",

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doi = "10.1146/annurev-physchem-040215-112347",

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AU - Chulhai, Dhabih V.

AU - Hu, Zhongwei

AU - Moore, Justin E.

AU - Chen, Xing

AU - Jensen, Lasse

N1 - Funding Information: We appreciate the generous support of the US National Science Foundation (NSF-CHE- 1266032) and of the UK Engineering and Physical Sciences Research Council (EP/K032062/1). We are grateful to Gilbert Nathanson, Duncan Bruce, John Slattery, George Schatz, Brooks Marshall, Simon Purcell, and Matthew Costen for many helpful discussions Publisher Copyright: Copyright © 2016 by Annual Reviews. All rights reserved.

PY - 2016/5/27

Y1 - 2016/5/27

N2 - The vibrational spectroscopy of molecules adsorbed on metal nanoparticles can be enhanced by many orders of magnitude so that the detection and identification of single molecules are possible. The enhancement of most linear and nonlinear vibrational spectroscopies has been demonstrated. In this review, we discuss theoretical approaches to understanding linear and nonlinear surface-enhanced vibrational spectroscopies. A unified description of enhancement mechanisms classified as either electromagnetic or chemical in nature is presented. Emphasis is placed on understanding the spectral changes necessary for interpretation of linear and nonlinear surface-enhanced vibrational spectroscopies.

AB - The vibrational spectroscopy of molecules adsorbed on metal nanoparticles can be enhanced by many orders of magnitude so that the detection and identification of single molecules are possible. The enhancement of most linear and nonlinear vibrational spectroscopies has been demonstrated. In this review, we discuss theoretical approaches to understanding linear and nonlinear surface-enhanced vibrational spectroscopies. A unified description of enhancement mechanisms classified as either electromagnetic or chemical in nature is presented. Emphasis is placed on understanding the spectral changes necessary for interpretation of linear and nonlinear surface-enhanced vibrational spectroscopies.

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JO - Annual Review of Physical Chemistry

JF - Annual Review of Physical Chemistry

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Theory of Linear and Nonlinear Surface-Enhanced Vibrational Spectroscopies

Abstract

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