Thermodynamic modeling of the indium-palladium system

Chao Jiang; Zi Kui Liu

doi:10.1007/s11661-002-0235-x

Thermodynamic modeling of the indium-palladium system

Chao Jiang, Zi Kui Liu

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The thermochemical and phase-equilibrium data of the In-Pd binary system were critically reviewed. A self-consistent thermodynamic description of the system was obtained using the CALPHAD approach. Eight intermetallic compounds were considered in the system. The InPd(B2) compound was described by a two-sublattice model. The compounds In₇Pd₃, In₃Pd₂, In₃Pd₅, αInPd₂, and αInPd₃, with negligible homogeneity ranges, were modeled as stoichiometric compounds. βInPd₂ and βInPd₃ were treated as stoichiometric compounds due to a lack of experimental information. Model calculations agreed satisfactorily with most existing experimental data. The thermodynamic factor for the InPd(B2) compound was also predicted based on the present thermodynamic description.

Original language	English (US)
Pages (from-to)	3597-3603
Number of pages	7
Journal	Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science
Volume	33
Issue number	12
DOIs	https://doi.org/10.1007/s11661-002-0235-x
State	Published - Dec 2002

All Science Journal Classification (ASJC) codes

Condensed Matter Physics
Mechanics of Materials
Metals and Alloys

Access to Document

10.1007/s11661-002-0235-x

Fingerprint Dive into the research topics of 'Thermodynamic modeling of the indium-palladium system'. Together they form a unique fingerprint.

Cite this

@article{1a5db6db1b414f37ae1f741c85d4683d,

title = "Thermodynamic modeling of the indium-palladium system",

abstract = "The thermochemical and phase-equilibrium data of the In-Pd binary system were critically reviewed. A self-consistent thermodynamic description of the system was obtained using the CALPHAD approach. Eight intermetallic compounds were considered in the system. The InPd(B2) compound was described by a two-sublattice model. The compounds In7Pd3, In3Pd2, In3Pd5, αInPd2, and αInPd3, with negligible homogeneity ranges, were modeled as stoichiometric compounds. βInPd2 and βInPd3 were treated as stoichiometric compounds due to a lack of experimental information. Model calculations agreed satisfactorily with most existing experimental data. The thermodynamic factor for the InPd(B2) compound was also predicted based on the present thermodynamic description.",

author = "Chao Jiang and Liu, {Zi Kui}",

year = "2002",

month = dec,

doi = "10.1007/s11661-002-0235-x",

language = "English (US)",

volume = "33",

pages = "3597--3603",

journal = "Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science",

issn = "1073-5623",

publisher = "Springer Boston",

number = "12",

}

TY - JOUR

T1 - Thermodynamic modeling of the indium-palladium system

AU - Jiang, Chao

AU - Liu, Zi Kui

PY - 2002/12

Y1 - 2002/12

N2 - The thermochemical and phase-equilibrium data of the In-Pd binary system were critically reviewed. A self-consistent thermodynamic description of the system was obtained using the CALPHAD approach. Eight intermetallic compounds were considered in the system. The InPd(B2) compound was described by a two-sublattice model. The compounds In7Pd3, In3Pd2, In3Pd5, αInPd2, and αInPd3, with negligible homogeneity ranges, were modeled as stoichiometric compounds. βInPd2 and βInPd3 were treated as stoichiometric compounds due to a lack of experimental information. Model calculations agreed satisfactorily with most existing experimental data. The thermodynamic factor for the InPd(B2) compound was also predicted based on the present thermodynamic description.

AB - The thermochemical and phase-equilibrium data of the In-Pd binary system were critically reviewed. A self-consistent thermodynamic description of the system was obtained using the CALPHAD approach. Eight intermetallic compounds were considered in the system. The InPd(B2) compound was described by a two-sublattice model. The compounds In7Pd3, In3Pd2, In3Pd5, αInPd2, and αInPd3, with negligible homogeneity ranges, were modeled as stoichiometric compounds. βInPd2 and βInPd3 were treated as stoichiometric compounds due to a lack of experimental information. Model calculations agreed satisfactorily with most existing experimental data. The thermodynamic factor for the InPd(B2) compound was also predicted based on the present thermodynamic description.

UR - http://www.scopus.com/inward/record.url?scp=0036992213&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0036992213&partnerID=8YFLogxK

U2 - 10.1007/s11661-002-0235-x

DO - 10.1007/s11661-002-0235-x

M3 - Article

AN - SCOPUS:0036992213

VL - 33

SP - 3597

EP - 3603

JO - Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science

JF - Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science

SN - 1073-5623

IS - 12

ER -