Thermodynamic signature of the onset of caged dynamics in glass-forming liquids

Sudesh Kamath; Ralph H. Colby; Sanat K. Kumar; Jörg Baschnagel

doi:10.1063/1.1433498

Thermodynamic signature of the onset of caged dynamics in glass-forming liquids

Sudesh Kamath, Ralph H. Colby, Sanat K. Kumar, Jörg Baschnagel

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23 Scopus citations

Abstract

Considering the immediate vicinity of an onset temperature, T_A where system dynamics just begin to experience caging effects, the thermodynamics of supercooled liquids was examined. It was noticed on analyzing the simulation data from polymer model and from small molecule mixtures that the configurational entropy becomes strongly temperature dependent below T_A. The thermodynamic connection to the localized dynamics of glass-forming liquids was established because the diffusion coefficient followed the Adam-Gibbs relationship.

Original language	English (US)
Pages (from-to)	865-868
Number of pages	4
Journal	Journal of Chemical Physics
Volume	116
Issue number	3
DOIs	https://doi.org/10.1063/1.1433498
State	Published - Jan 15 2002

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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abstract = "Considering the immediate vicinity of an onset temperature, TA where system dynamics just begin to experience caging effects, the thermodynamics of supercooled liquids was examined. It was noticed on analyzing the simulation data from polymer model and from small molecule mixtures that the configurational entropy becomes strongly temperature dependent below TA. The thermodynamic connection to the localized dynamics of glass-forming liquids was established because the diffusion coefficient followed the Adam-Gibbs relationship.",

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Thermodynamic signature of the onset of caged dynamics in glass-forming liquids

Abstract

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