Thermodynamics of Highly Solvated Ternary Liquid Metal Solutions

Montgomery Meigs Alger, Charles A. Eckert

Research output: Contribution to journalArticle

11 Scopus citations

Abstract

Negative deviations from Raoult's law in ternary liquid metal mixtures are modeled with the multicomponent ideal chemical theory (MICT) model. Expressions for the activity coefficients, partial molar enthalpies, and the stability function are derived and given as a function of the model parameters: Gibbs energy of compound formation, enthalpy of compound formation, and the heat capacity change of compound formation. Model predictions are given and compared with experimental measurements for three ternary magnesium systems. Experimental measurements of the magnesium activity coefficient at 1073 K in the Mg-Sb-BI and Mg-Pb-BI systems are presented and compared with MICT model predictions.

Original languageEnglish (US)
Pages (from-to)416-421
Number of pages6
JournalIndustrial and Engineering Chemistry Fundamentals
Volume25
Issue number3
DOIs
StatePublished - Jan 1 1986

All Science Journal Classification (ASJC) codes

  • Engineering(all)

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