Total synthesis and structure proof of (3E,8E)-suspensolide

Merle A. Battiste, James R. Rocca, Roman L. Wydra, James Homer Tumlinson, III, Tatsuji Chuman

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

A new macrolide, E,E-suspensolide (1), was prepared in six steps from mesityl oxide. The stereochemistries of intermediate isomers were assigned principally from their 13C NMR spectra. An isomeric macrolide, Z,E-suspensolide (2), was also prepared.

Original languageEnglish (US)
Pages (from-to)6565-6567
Number of pages3
JournalTetrahedron Letters
Volume29
Issue number50
DOIs
StatePublished - Jan 1 1988

Fingerprint

Macrolides
Stereochemistry
Isomers
Nuclear magnetic resonance
mesityl oxide
Carbon-13 Magnetic Resonance Spectroscopy

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Battiste, Merle A. ; Rocca, James R. ; Wydra, Roman L. ; Tumlinson, III, James Homer ; Chuman, Tatsuji. / Total synthesis and structure proof of (3E,8E)-suspensolide. In: Tetrahedron Letters. 1988 ; Vol. 29, No. 50. pp. 6565-6567.
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Total synthesis and structure proof of (3E,8E)-suspensolide. / Battiste, Merle A.; Rocca, James R.; Wydra, Roman L.; Tumlinson, III, James Homer; Chuman, Tatsuji.

In: Tetrahedron Letters, Vol. 29, No. 50, 01.01.1988, p. 6565-6567.

Research output: Contribution to journalArticle

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