Towards electrocaloric heat pump - A relaxor ferroelectric polymer exhibiting large electrocaloric response at low electric field

Xin Chen, Wenhan Xu, Biao Lu, Tian Zhang, Qing Wang, Q. M. Zhang

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A polymer that generates large cooling under applied voltage is attractive for many applications. The past decade has witnessed the discovery and advancement in electrocaloric (EC) polymers, which display large electric field induced temperature and entropy changes. However, in contrast to the burgeoning literature on large electrocaloric effects (ECEs) in various ferroelectric materials, there are no EC devices employing these EC polymers, demonstrating a meaningful cooling power. Here, we show that it is the dielectric breakdown, the weakest link problem, in EC materials which poses a critical barrier for transitioning these advanced EC materials to practical EC coolers. Hence, high quality EC films and high performance of EC materials, exhibiting large ECE at low electric fields, are required to overcome this barrier. Here, we show that by expanding the compositions in EC polymers, a relaxor tetrapolymer exhibits a critical end point at low electric fields, leading to large ECE induced at low electric fields.

Original languageEnglish (US)
Article number113902
JournalApplied Physics Letters
Volume113
Issue number11
DOIs
StatePublished - Sep 10 2018

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heat pumps
electric fields
polymers
cooling
ferroelectric materials
coolers
breakdown
entropy
electric potential
temperature

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy (miscellaneous)

Cite this

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abstract = "A polymer that generates large cooling under applied voltage is attractive for many applications. The past decade has witnessed the discovery and advancement in electrocaloric (EC) polymers, which display large electric field induced temperature and entropy changes. However, in contrast to the burgeoning literature on large electrocaloric effects (ECEs) in various ferroelectric materials, there are no EC devices employing these EC polymers, demonstrating a meaningful cooling power. Here, we show that it is the dielectric breakdown, the weakest link problem, in EC materials which poses a critical barrier for transitioning these advanced EC materials to practical EC coolers. Hence, high quality EC films and high performance of EC materials, exhibiting large ECE at low electric fields, are required to overcome this barrier. Here, we show that by expanding the compositions in EC polymers, a relaxor tetrapolymer exhibits a critical end point at low electric fields, leading to large ECE induced at low electric fields.",
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Towards electrocaloric heat pump - A relaxor ferroelectric polymer exhibiting large electrocaloric response at low electric field. / Chen, Xin; Xu, Wenhan; Lu, Biao; Zhang, Tian; Wang, Qing; Zhang, Q. M.

In: Applied Physics Letters, Vol. 113, No. 11, 113902, 10.09.2018.

Research output: Contribution to journalArticle

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AU - Zhang, Q. M.

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