trans-diaquabis(2-thienyl 2-pyridyl ketone-O,N)copper(II) tetrafluoroborate

Shaun O. Sommerer, Timothy L. Friebe, Alan John Jircitano, Cora E. Macbeth, Khalil A. Abboud

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The title complex, [Cu(C10H7NOS)2(H2O) 2](BF4)2, contains tetragonally elongated octahedral diaquabis(2-thienyl 2-pyridyl ketone)copper(II) cations counterbalanced with BF4- anions. The Cu atom resides on an inversion center and is bonded to the ligand through the pyridine N and the carbonyl O atoms [1.986(2) Å], with a bite angle of 81.39(10)°. The thiophene is not involved in coordination. The coordinated water molecules are hydrogen bridged to adjacent BF4- anions, linking the cation and anion in an extended chain.

Original languageEnglish (US)
Pages (from-to)178-179
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume54
Issue number2
DOIs
StatePublished - Feb 15 1998

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Ketones
Anions
Copper
Cations
Thiophenes
Atoms
Bites and Stings
Hydrogen
Ligands
Molecules
Water

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

Sommerer, Shaun O. ; Friebe, Timothy L. ; Jircitano, Alan John ; Macbeth, Cora E. ; Abboud, Khalil A. / trans-diaquabis(2-thienyl 2-pyridyl ketone-O,N)copper(II) tetrafluoroborate. In: Acta Crystallographica Section C: Crystal Structure Communications. 1998 ; Vol. 54, No. 2. pp. 178-179.
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abstract = "The title complex, [Cu(C10H7NOS)2(H2O) 2](BF4)2, contains tetragonally elongated octahedral diaquabis(2-thienyl 2-pyridyl ketone)copper(II) cations counterbalanced with BF4- anions. The Cu atom resides on an inversion center and is bonded to the ligand through the pyridine N and the carbonyl O atoms [1.986(2) {\AA}], with a bite angle of 81.39(10)°. The thiophene is not involved in coordination. The coordinated water molecules are hydrogen bridged to adjacent BF4- anions, linking the cation and anion in an extended chain.",
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trans-diaquabis(2-thienyl 2-pyridyl ketone-O,N)copper(II) tetrafluoroborate. / Sommerer, Shaun O.; Friebe, Timothy L.; Jircitano, Alan John; Macbeth, Cora E.; Abboud, Khalil A.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 54, No. 2, 15.02.1998, p. 178-179.

Research output: Contribution to journalArticle

TY - JOUR

T1 - trans-diaquabis(2-thienyl 2-pyridyl ketone-O,N)copper(II) tetrafluoroborate

AU - Sommerer, Shaun O.

AU - Friebe, Timothy L.

AU - Jircitano, Alan John

AU - Macbeth, Cora E.

AU - Abboud, Khalil A.

PY - 1998/2/15

Y1 - 1998/2/15

N2 - The title complex, [Cu(C10H7NOS)2(H2O) 2](BF4)2, contains tetragonally elongated octahedral diaquabis(2-thienyl 2-pyridyl ketone)copper(II) cations counterbalanced with BF4- anions. The Cu atom resides on an inversion center and is bonded to the ligand through the pyridine N and the carbonyl O atoms [1.986(2) Å], with a bite angle of 81.39(10)°. The thiophene is not involved in coordination. The coordinated water molecules are hydrogen bridged to adjacent BF4- anions, linking the cation and anion in an extended chain.

AB - The title complex, [Cu(C10H7NOS)2(H2O) 2](BF4)2, contains tetragonally elongated octahedral diaquabis(2-thienyl 2-pyridyl ketone)copper(II) cations counterbalanced with BF4- anions. The Cu atom resides on an inversion center and is bonded to the ligand through the pyridine N and the carbonyl O atoms [1.986(2) Å], with a bite angle of 81.39(10)°. The thiophene is not involved in coordination. The coordinated water molecules are hydrogen bridged to adjacent BF4- anions, linking the cation and anion in an extended chain.

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JO - Acta Crystallographica Section C: Crystal Structure Communications

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