Trans-dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato) cobalt(II)

Jordan Oswald Lerach, Matthias Zeller, Brian D. Leskiw

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The Co atom of the title compound, [Co(C8H10F3O2)2(CH3OH)2], which is located on a crystallographic inversion center, exhibits a distorted octa-hedral geometry. The bidentate acetyl-acetonate-like ligands are in a trans arrangement. The plane through the acetyl-acetonate unit is tilted with respect to the CoO4 plane by 17.41 (7)°, which is in the same range as observed for similar Co(acac)2OR 2 derivatives. Via the methanol hydr-oxy groups, each mol-ecule participates in two pairs of inter-molecular hydrogen bonds that create a network of hydrogen-bonded chains along the direction of the a axis.

Original languageEnglish (US)
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number11
DOIs
StatePublished - Oct 5 2007

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Cobalt
Hydrogen
Hydrogen bonds
Methanol
cobalt
methyl alcohol
Ligands
inversions
hydrogen bonds
Derivatives
Atoms
ligands
Geometry
hydrogen
geometry
atoms
acetyl acetonate
Direction compound

All Science Journal Classification (ASJC) codes

  • Structural Biology
  • Condensed Matter Physics

Cite this

Lerach, Jordan Oswald ; Zeller, Matthias ; Leskiw, Brian D. / Trans-dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato) cobalt(II). In: Acta Crystallographica Section E: Structure Reports Online. 2007 ; Vol. 63, No. 11.
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Trans-dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato) cobalt(II). / Lerach, Jordan Oswald; Zeller, Matthias; Leskiw, Brian D.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 11, 05.10.2007.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Trans-dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato) cobalt(II)

AU - Lerach, Jordan Oswald

AU - Zeller, Matthias

AU - Leskiw, Brian D.

PY - 2007/10/5

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N2 - The Co atom of the title compound, [Co(C8H10F3O2)2(CH3OH)2], which is located on a crystallographic inversion center, exhibits a distorted octa-hedral geometry. The bidentate acetyl-acetonate-like ligands are in a trans arrangement. The plane through the acetyl-acetonate unit is tilted with respect to the CoO4 plane by 17.41 (7)°, which is in the same range as observed for similar Co(acac)2OR 2 derivatives. Via the methanol hydr-oxy groups, each mol-ecule participates in two pairs of inter-molecular hydrogen bonds that create a network of hydrogen-bonded chains along the direction of the a axis.

AB - The Co atom of the title compound, [Co(C8H10F3O2)2(CH3OH)2], which is located on a crystallographic inversion center, exhibits a distorted octa-hedral geometry. The bidentate acetyl-acetonate-like ligands are in a trans arrangement. The plane through the acetyl-acetonate unit is tilted with respect to the CoO4 plane by 17.41 (7)°, which is in the same range as observed for similar Co(acac)2OR 2 derivatives. Via the methanol hydr-oxy groups, each mol-ecule participates in two pairs of inter-molecular hydrogen bonds that create a network of hydrogen-bonded chains along the direction of the a axis.

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