Tunable intraparticle frameworks for creating complex heterostructured nanoparticle libraries

Julie L. Fenton, Benjamin C. Steimle, Raymond E. Schaak

Research output: Contribution to journalArticle

92 Scopus citations

Abstract

Complex heterostructured nanoparticles with precisely defined materials and interfaces are important for many applications. However, rationally incorporating such features into nanoparticles with rigorous morphology control remains a synthetic bottleneck. We define a modular divergent synthesis strategy that progressively transforms simple nanoparticle synthons into increasingly sophisticated products. We introduce a series of tunable interfaces into zero-, one-, and two-dimensional copper sulfide nanoparticles using cation exchange reactions. Subsequent manipulation of these intraparticle frameworks yielded a library of 47 distinct heterostructured metal sulfide derivatives, including particles that contain asymmetric, patchy, porous, and sculpted nanoarchitectures. This generalizable mix-and-match strategy provides predictable retrosynthetic pathways to complex nanoparticle features that are otherwise inaccessible.

Original languageEnglish (US)
Pages (from-to)513-517
Number of pages5
JournalScience
Volume360
Issue number6388
DOIs
StatePublished - May 4 2018

All Science Journal Classification (ASJC) codes

  • General

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