Understanding Glass through Differential Scanning Calorimetry

Qiuju Zheng, Yanfei Zhang, Maziar Montazerian, Ozgur Gulbiten, John Mauro, Edgar D. Zanotto, Yuanzheng Yue

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Differential scanning calorimetry (DSC) is a powerful tool to address some of the most challenging issues in glass science and technology, such as the nonequilibrium nature of the glassy state and the detailed thermodynamics and kinetics of glass-forming systems during glass transition, relaxation, rejuvenation, polyamorphic transition, and crystallization. The utility of the DSC technique spans across all glass-forming chemistries, including oxide, chalcogenide, metallic, and organic systems, as well as recently discovered metal-organic framework glass-forming systems. Here we present a comprehensive review of the many applications of DSC in glass science with focus on glass transition, relaxation, polyamorphism, and crystallization phenomena. We also emphasize recent advances in DSC characterization technology, including flash DSC and temperature-modulated DSC. This review demonstrates how DSC studies have led to a multitude of relevant advances in the understanding of glass physics, chemistry, and even technology.

Original languageEnglish (US)
Pages (from-to)7848-7939
Number of pages92
JournalChemical Reviews
Volume119
Issue number13
DOIs
StatePublished - Jul 10 2019

Fingerprint

Differential scanning calorimetry
Glass
Crystallization
Glass transition
Oxides
Physics
Metals
Thermodynamics
Kinetics
Temperature

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Zheng, Q., Zhang, Y., Montazerian, M., Gulbiten, O., Mauro, J., Zanotto, E. D., & Yue, Y. (2019). Understanding Glass through Differential Scanning Calorimetry. Chemical Reviews, 119(13), 7848-7939. https://doi.org/10.1021/acs.chemrev.8b00510
Zheng, Qiuju ; Zhang, Yanfei ; Montazerian, Maziar ; Gulbiten, Ozgur ; Mauro, John ; Zanotto, Edgar D. ; Yue, Yuanzheng. / Understanding Glass through Differential Scanning Calorimetry. In: Chemical Reviews. 2019 ; Vol. 119, No. 13. pp. 7848-7939.
@article{b5b1e0c4c0104cce951f2c69f73e5143,
title = "Understanding Glass through Differential Scanning Calorimetry",
abstract = "Differential scanning calorimetry (DSC) is a powerful tool to address some of the most challenging issues in glass science and technology, such as the nonequilibrium nature of the glassy state and the detailed thermodynamics and kinetics of glass-forming systems during glass transition, relaxation, rejuvenation, polyamorphic transition, and crystallization. The utility of the DSC technique spans across all glass-forming chemistries, including oxide, chalcogenide, metallic, and organic systems, as well as recently discovered metal-organic framework glass-forming systems. Here we present a comprehensive review of the many applications of DSC in glass science with focus on glass transition, relaxation, polyamorphism, and crystallization phenomena. We also emphasize recent advances in DSC characterization technology, including flash DSC and temperature-modulated DSC. This review demonstrates how DSC studies have led to a multitude of relevant advances in the understanding of glass physics, chemistry, and even technology.",
author = "Qiuju Zheng and Yanfei Zhang and Maziar Montazerian and Ozgur Gulbiten and John Mauro and Zanotto, {Edgar D.} and Yuanzheng Yue",
year = "2019",
month = "7",
day = "10",
doi = "10.1021/acs.chemrev.8b00510",
language = "English (US)",
volume = "119",
pages = "7848--7939",
journal = "Chemical Reviews",
issn = "0009-2665",
publisher = "American Chemical Society",
number = "13",

}

Zheng, Q, Zhang, Y, Montazerian, M, Gulbiten, O, Mauro, J, Zanotto, ED & Yue, Y 2019, 'Understanding Glass through Differential Scanning Calorimetry', Chemical Reviews, vol. 119, no. 13, pp. 7848-7939. https://doi.org/10.1021/acs.chemrev.8b00510

Understanding Glass through Differential Scanning Calorimetry. / Zheng, Qiuju; Zhang, Yanfei; Montazerian, Maziar; Gulbiten, Ozgur; Mauro, John; Zanotto, Edgar D.; Yue, Yuanzheng.

In: Chemical Reviews, Vol. 119, No. 13, 10.07.2019, p. 7848-7939.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Understanding Glass through Differential Scanning Calorimetry

AU - Zheng, Qiuju

AU - Zhang, Yanfei

AU - Montazerian, Maziar

AU - Gulbiten, Ozgur

AU - Mauro, John

AU - Zanotto, Edgar D.

AU - Yue, Yuanzheng

PY - 2019/7/10

Y1 - 2019/7/10

N2 - Differential scanning calorimetry (DSC) is a powerful tool to address some of the most challenging issues in glass science and technology, such as the nonequilibrium nature of the glassy state and the detailed thermodynamics and kinetics of glass-forming systems during glass transition, relaxation, rejuvenation, polyamorphic transition, and crystallization. The utility of the DSC technique spans across all glass-forming chemistries, including oxide, chalcogenide, metallic, and organic systems, as well as recently discovered metal-organic framework glass-forming systems. Here we present a comprehensive review of the many applications of DSC in glass science with focus on glass transition, relaxation, polyamorphism, and crystallization phenomena. We also emphasize recent advances in DSC characterization technology, including flash DSC and temperature-modulated DSC. This review demonstrates how DSC studies have led to a multitude of relevant advances in the understanding of glass physics, chemistry, and even technology.

AB - Differential scanning calorimetry (DSC) is a powerful tool to address some of the most challenging issues in glass science and technology, such as the nonequilibrium nature of the glassy state and the detailed thermodynamics and kinetics of glass-forming systems during glass transition, relaxation, rejuvenation, polyamorphic transition, and crystallization. The utility of the DSC technique spans across all glass-forming chemistries, including oxide, chalcogenide, metallic, and organic systems, as well as recently discovered metal-organic framework glass-forming systems. Here we present a comprehensive review of the many applications of DSC in glass science with focus on glass transition, relaxation, polyamorphism, and crystallization phenomena. We also emphasize recent advances in DSC characterization technology, including flash DSC and temperature-modulated DSC. This review demonstrates how DSC studies have led to a multitude of relevant advances in the understanding of glass physics, chemistry, and even technology.

UR - http://www.scopus.com/inward/record.url?scp=85066904036&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85066904036&partnerID=8YFLogxK

U2 - 10.1021/acs.chemrev.8b00510

DO - 10.1021/acs.chemrev.8b00510

M3 - Article

C2 - 31120738

AN - SCOPUS:85066904036

VL - 119

SP - 7848

EP - 7939

JO - Chemical Reviews

JF - Chemical Reviews

SN - 0009-2665

IS - 13

ER -

Zheng Q, Zhang Y, Montazerian M, Gulbiten O, Mauro J, Zanotto ED et al. Understanding Glass through Differential Scanning Calorimetry. Chemical Reviews. 2019 Jul 10;119(13):7848-7939. https://doi.org/10.1021/acs.chemrev.8b00510