Using a mathematical model of a weathering clast to explore the effects of curvature on weathering

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

For the first time, we show that rind thicknesses developed on surfaces of a clast with different values of curvature can be used to estimate the duration of clast weathering. To obtain an analytical expression for the velocity of the curvilinear weathering front on a clast of arbitrary shape, we approximate our previous multi-mineral reactive-diffusion model and explore a simplified 2-D model numerically and analytically.Our analysis documents that with increasing curvature of the weathering front, the mathematical description of weathering advance is equivalent to that derived for advection as the dominant solute transport mechanism, even for the case where transport is occurring by diffusion only. Specifically, for a curvilinear weathering front with constant curvature K<0, diffusivity (D), and porosity (ϕ), the normal component of the weathering advance rate can be calculated using an advection-like term where the advection velocity v can be expressed as v=Dϕ|K|. Therefore, at points along the rind-core interface with K<0, rind thickness is directly proportional to the absolute value of the curvature of the core-rind interface. The reaction front thickness also increases with K. These inferences are in agreement with field observations. This quantitative analysis allows an assessment of the duration of weathering if certain parameters are known. For example, using the difference in curvature observed at two positions for a clast that weathered in Guadeloupe (0.12mm-1 and 0.018mm-1) and the corresponding rind thickness difference (35.8mm and 20.6mm), we estimated the duration of weathering to be about 118ky, which is consistent with the weathering ages previously determined by U-series isotope disequilibrium.

Original languageEnglish (US)
Pages (from-to)88-99
Number of pages12
JournalChemical Geology
Volume404
DOIs
StatePublished - May 6 2015

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Weathering
clast
curvature
weathering
Mathematical models
Advection
advection
advance rate
effect
Solute transport
solute transport
Isotopes
disequilibrium
diffusivity
quantitative analysis
Minerals
Porosity
porosity
isotope
mineral

All Science Journal Classification (ASJC) codes

  • Geology
  • Geochemistry and Petrology

Cite this

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title = "Using a mathematical model of a weathering clast to explore the effects of curvature on weathering",
abstract = "For the first time, we show that rind thicknesses developed on surfaces of a clast with different values of curvature can be used to estimate the duration of clast weathering. To obtain an analytical expression for the velocity of the curvilinear weathering front on a clast of arbitrary shape, we approximate our previous multi-mineral reactive-diffusion model and explore a simplified 2-D model numerically and analytically.Our analysis documents that with increasing curvature of the weathering front, the mathematical description of weathering advance is equivalent to that derived for advection as the dominant solute transport mechanism, even for the case where transport is occurring by diffusion only. Specifically, for a curvilinear weathering front with constant curvature K<0, diffusivity (D), and porosity (ϕ), the normal component of the weathering advance rate can be calculated using an advection-like term where the advection velocity v can be expressed as v=Dϕ|K|. Therefore, at points along the rind-core interface with K<0, rind thickness is directly proportional to the absolute value of the curvature of the core-rind interface. The reaction front thickness also increases with K. These inferences are in agreement with field observations. This quantitative analysis allows an assessment of the duration of weathering if certain parameters are known. For example, using the difference in curvature observed at two positions for a clast that weathered in Guadeloupe (0.12mm-1 and 0.018mm-1) and the corresponding rind thickness difference (35.8mm and 20.6mm), we estimated the duration of weathering to be about 118ky, which is consistent with the weathering ages previously determined by U-series isotope disequilibrium.",
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Using a mathematical model of a weathering clast to explore the effects of curvature on weathering. / Lebedeva, Marina Ivanovna; Sak, Peter Benjamin; Ma, L.; Brantley, Susan Louise.

In: Chemical Geology, Vol. 404, 06.05.2015, p. 88-99.

Research output: Contribution to journalArticle

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AU - Lebedeva, Marina Ivanovna

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