Vibrational Sum Frequency Generation (SFG) Analysis of Ferroelectric Response of PVDF-Based Copolymer and Terpolymer

Inseok Chae, Saad Ahmed, Hassene Ben Atitallah, Jiawei Luo, Qing Wang, Zoubeida Ounaies, Seong Kim

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

In poly(vinylidene difluoride) (PVDF)-based polymers, the alignment of dipoles of the crystalline β phase with all-trans conformations is responsible for ferroelectricity; however, there is a lack of direct spectroscopic evidence for this phenomenon. We report in situ monitoring of the molecular orientations associated with ferroelectric responses of PVDF-based polymers using vibrational sum frequency generation (SFG) spectroscopy. The orientation of CH2 groups with respect to the −(CH2CF2)n- chain axis of the poled β domains in a PVDF copolymer was determined from the SFG dependence of an uniaxially aligned sample on the laser polarization and azimuthal angle. The relative intensities of CH2 symmetric and asymmetric stretch modes as well as their total intensities revealed the transformation of the all-trans conformation domains during the electrical poling of PVDF based co- and terpolymer films.

Original languageEnglish (US)
Pages (from-to)2838-2844
Number of pages7
JournalMacromolecules
Volume50
Issue number7
DOIs
StatePublished - Apr 11 2017

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Terpolymers
Vibrational spectra
Ferroelectric materials
Conformations
Polymers
Copolymers
Ferroelectricity
Molecular orientation
Spectroscopy
Polarization
Crystalline materials
Lasers
Monitoring

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

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abstract = "In poly(vinylidene difluoride) (PVDF)-based polymers, the alignment of dipoles of the crystalline β phase with all-trans conformations is responsible for ferroelectricity; however, there is a lack of direct spectroscopic evidence for this phenomenon. We report in situ monitoring of the molecular orientations associated with ferroelectric responses of PVDF-based polymers using vibrational sum frequency generation (SFG) spectroscopy. The orientation of CH2 groups with respect to the −(CH2CF2)n- chain axis of the poled β domains in a PVDF copolymer was determined from the SFG dependence of an uniaxially aligned sample on the laser polarization and azimuthal angle. The relative intensities of CH2 symmetric and asymmetric stretch modes as well as their total intensities revealed the transformation of the all-trans conformation domains during the electrical poling of PVDF based co- and terpolymer films.",
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Vibrational Sum Frequency Generation (SFG) Analysis of Ferroelectric Response of PVDF-Based Copolymer and Terpolymer. / Chae, Inseok; Ahmed, Saad; Atitallah, Hassene Ben; Luo, Jiawei; Wang, Qing; Ounaies, Zoubeida; Kim, Seong.

In: Macromolecules, Vol. 50, No. 7, 11.04.2017, p. 2838-2844.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Vibrational Sum Frequency Generation (SFG) Analysis of Ferroelectric Response of PVDF-Based Copolymer and Terpolymer

AU - Chae, Inseok

AU - Ahmed, Saad

AU - Atitallah, Hassene Ben

AU - Luo, Jiawei

AU - Wang, Qing

AU - Ounaies, Zoubeida

AU - Kim, Seong

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N2 - In poly(vinylidene difluoride) (PVDF)-based polymers, the alignment of dipoles of the crystalline β phase with all-trans conformations is responsible for ferroelectricity; however, there is a lack of direct spectroscopic evidence for this phenomenon. We report in situ monitoring of the molecular orientations associated with ferroelectric responses of PVDF-based polymers using vibrational sum frequency generation (SFG) spectroscopy. The orientation of CH2 groups with respect to the −(CH2CF2)n- chain axis of the poled β domains in a PVDF copolymer was determined from the SFG dependence of an uniaxially aligned sample on the laser polarization and azimuthal angle. The relative intensities of CH2 symmetric and asymmetric stretch modes as well as their total intensities revealed the transformation of the all-trans conformation domains during the electrical poling of PVDF based co- and terpolymer films.

AB - In poly(vinylidene difluoride) (PVDF)-based polymers, the alignment of dipoles of the crystalline β phase with all-trans conformations is responsible for ferroelectricity; however, there is a lack of direct spectroscopic evidence for this phenomenon. We report in situ monitoring of the molecular orientations associated with ferroelectric responses of PVDF-based polymers using vibrational sum frequency generation (SFG) spectroscopy. The orientation of CH2 groups with respect to the −(CH2CF2)n- chain axis of the poled β domains in a PVDF copolymer was determined from the SFG dependence of an uniaxially aligned sample on the laser polarization and azimuthal angle. The relative intensities of CH2 symmetric and asymmetric stretch modes as well as their total intensities revealed the transformation of the all-trans conformation domains during the electrical poling of PVDF based co- and terpolymer films.

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