Viscoelastic diffusion

J. S. Vrentas, C. M. Vrentas

Research output: Contribution to journalArticle

14 Scopus citations

Abstract

A constitutive equation is proposed for the viscoelastic diffusion flux, and this equation is used to calculate sorption curves for differential step-change sorption experiments. The predictions of the theory are shown to be consistent with eight experimental observations that report a wide range of diffusional behaviors for polymer-solvent systems.

Original languageEnglish (US)
Pages (from-to)1529-1547
Number of pages19
JournalJournal of Polymer Science, Part B: Polymer Physics
Volume39
Issue number13
DOIs
StatePublished - Jul 1 2001

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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