W-shaped permeability evolution of coal with supercritical CO2 phase transition

Sheng Zhi, Derek Elsworth, Liyuan Liu

Research output: Contribution to journalArticle

Abstract

Gaseous CO2 becomes a supercritical liquid when temperature and pressure transit the critical point (31.1 °C and 7.4 MPa) – a typical state for CO2 storage for carbon sequestration and CO2 injection in enhanced coalbed methane/shale recovery. Therefore, it is essential to define the evolution of coal permeability inclusive of this phase transition. This study presents experimental measurements of coal permeability across the CO2/SCCO2 transition over typical ranges of confining stress (3–15 MPa) and pore pressures (1–13 MPa) at a constant temperature of 40 °C. The results show that contrary to the typical U-shaped permeability -vs- pressure evolution in the subcritical region, a second permeability minimum occurs in the vicinity of the critical pressure – even after the impacts of viscosity transition are accommodated. Permeability to SCCO2 is almost two-orders-of-magnitude smaller than its initial permeability to subcritical-CO2. The phase transition from subcritical to supercritical state controls the W-shaped coal permeability profile. Permeability in the same coal is indexed relative to non-sorbing Helium (He) and slightly-adsorbing Nitrogen (N2) to probe the origins of the W-shaped permeability profile around the SCCO2 phase transition. Observed irreversible changes in mechanical properties driven by the SCCO2 phase transition are linked to the observed permeability reduction. First, observed reductions in coal strength and stiffness after SCCO2 saturation indicate a significant weakening effect - SCCO2 acts as a strong plasticizer enabling rearrangement of the physical structure and adding molecular mobility. The softened coal responds to increased compressional deformation and cleat closure under the same effective stress, resulting in a net permeability reduction in the supercritical region countering any influences of permeability-enhancing microcrack formation. Second, the SCCO2 permeability is further reduced by a large increase in sorption-induced swelling observed after the transition. Measured swelling strains indicate a > 90% increase in SCCO2 sorption-induced swelling relative to Langmuir response at 13 MPa. The enlarged SCCO2 adsorption capacity presumably results from the slightly polar nature of the SCCO2 dimer and the increased SCCO2 density. Permeability reduction due to plasticization and increased swelling is shown to dominate over permeability increases driven by brittle damage.

Original languageEnglish (US)
Article number103221
JournalInternational Journal of Coal Geology
Volume211
DOIs
StatePublished - Jul 1 2019

Fingerprint

phase transition
Phase transitions
Coal
permeability
coal
Swelling
Sorption
swelling
Pore pressure
Plasticizers
Microcracks
Shale
Dimers
Helium
Stiffness
Viscosity
Nitrogen
Adsorption
Recovery
Mechanical properties

All Science Journal Classification (ASJC) codes

  • Fuel Technology
  • Geology
  • Economic Geology
  • Stratigraphy

Cite this

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title = "W-shaped permeability evolution of coal with supercritical CO2 phase transition",
abstract = "Gaseous CO2 becomes a supercritical liquid when temperature and pressure transit the critical point (31.1 °C and 7.4 MPa) – a typical state for CO2 storage for carbon sequestration and CO2 injection in enhanced coalbed methane/shale recovery. Therefore, it is essential to define the evolution of coal permeability inclusive of this phase transition. This study presents experimental measurements of coal permeability across the CO2/SCCO2 transition over typical ranges of confining stress (3–15 MPa) and pore pressures (1–13 MPa) at a constant temperature of 40 °C. The results show that contrary to the typical U-shaped permeability -vs- pressure evolution in the subcritical region, a second permeability minimum occurs in the vicinity of the critical pressure – even after the impacts of viscosity transition are accommodated. Permeability to SCCO2 is almost two-orders-of-magnitude smaller than its initial permeability to subcritical-CO2. The phase transition from subcritical to supercritical state controls the W-shaped coal permeability profile. Permeability in the same coal is indexed relative to non-sorbing Helium (He) and slightly-adsorbing Nitrogen (N2) to probe the origins of the W-shaped permeability profile around the SCCO2 phase transition. Observed irreversible changes in mechanical properties driven by the SCCO2 phase transition are linked to the observed permeability reduction. First, observed reductions in coal strength and stiffness after SCCO2 saturation indicate a significant weakening effect - SCCO2 acts as a strong plasticizer enabling rearrangement of the physical structure and adding molecular mobility. The softened coal responds to increased compressional deformation and cleat closure under the same effective stress, resulting in a net permeability reduction in the supercritical region countering any influences of permeability-enhancing microcrack formation. Second, the SCCO2 permeability is further reduced by a large increase in sorption-induced swelling observed after the transition. Measured swelling strains indicate a > 90{\%} increase in SCCO2 sorption-induced swelling relative to Langmuir response at 13 MPa. The enlarged SCCO2 adsorption capacity presumably results from the slightly polar nature of the SCCO2 dimer and the increased SCCO2 density. Permeability reduction due to plasticization and increased swelling is shown to dominate over permeability increases driven by brittle damage.",
author = "Sheng Zhi and Derek Elsworth and Liyuan Liu",
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W-shaped permeability evolution of coal with supercritical CO2 phase transition. / Zhi, Sheng; Elsworth, Derek; Liu, Liyuan.

In: International Journal of Coal Geology, Vol. 211, 103221, 01.07.2019.

Research output: Contribution to journalArticle

TY - JOUR

T1 - W-shaped permeability evolution of coal with supercritical CO2 phase transition

AU - Zhi, Sheng

AU - Elsworth, Derek

AU - Liu, Liyuan

PY - 2019/7/1

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N2 - Gaseous CO2 becomes a supercritical liquid when temperature and pressure transit the critical point (31.1 °C and 7.4 MPa) – a typical state for CO2 storage for carbon sequestration and CO2 injection in enhanced coalbed methane/shale recovery. Therefore, it is essential to define the evolution of coal permeability inclusive of this phase transition. This study presents experimental measurements of coal permeability across the CO2/SCCO2 transition over typical ranges of confining stress (3–15 MPa) and pore pressures (1–13 MPa) at a constant temperature of 40 °C. The results show that contrary to the typical U-shaped permeability -vs- pressure evolution in the subcritical region, a second permeability minimum occurs in the vicinity of the critical pressure – even after the impacts of viscosity transition are accommodated. Permeability to SCCO2 is almost two-orders-of-magnitude smaller than its initial permeability to subcritical-CO2. The phase transition from subcritical to supercritical state controls the W-shaped coal permeability profile. Permeability in the same coal is indexed relative to non-sorbing Helium (He) and slightly-adsorbing Nitrogen (N2) to probe the origins of the W-shaped permeability profile around the SCCO2 phase transition. Observed irreversible changes in mechanical properties driven by the SCCO2 phase transition are linked to the observed permeability reduction. First, observed reductions in coal strength and stiffness after SCCO2 saturation indicate a significant weakening effect - SCCO2 acts as a strong plasticizer enabling rearrangement of the physical structure and adding molecular mobility. The softened coal responds to increased compressional deformation and cleat closure under the same effective stress, resulting in a net permeability reduction in the supercritical region countering any influences of permeability-enhancing microcrack formation. Second, the SCCO2 permeability is further reduced by a large increase in sorption-induced swelling observed after the transition. Measured swelling strains indicate a > 90% increase in SCCO2 sorption-induced swelling relative to Langmuir response at 13 MPa. The enlarged SCCO2 adsorption capacity presumably results from the slightly polar nature of the SCCO2 dimer and the increased SCCO2 density. Permeability reduction due to plasticization and increased swelling is shown to dominate over permeability increases driven by brittle damage.

AB - Gaseous CO2 becomes a supercritical liquid when temperature and pressure transit the critical point (31.1 °C and 7.4 MPa) – a typical state for CO2 storage for carbon sequestration and CO2 injection in enhanced coalbed methane/shale recovery. Therefore, it is essential to define the evolution of coal permeability inclusive of this phase transition. This study presents experimental measurements of coal permeability across the CO2/SCCO2 transition over typical ranges of confining stress (3–15 MPa) and pore pressures (1–13 MPa) at a constant temperature of 40 °C. The results show that contrary to the typical U-shaped permeability -vs- pressure evolution in the subcritical region, a second permeability minimum occurs in the vicinity of the critical pressure – even after the impacts of viscosity transition are accommodated. Permeability to SCCO2 is almost two-orders-of-magnitude smaller than its initial permeability to subcritical-CO2. The phase transition from subcritical to supercritical state controls the W-shaped coal permeability profile. Permeability in the same coal is indexed relative to non-sorbing Helium (He) and slightly-adsorbing Nitrogen (N2) to probe the origins of the W-shaped permeability profile around the SCCO2 phase transition. Observed irreversible changes in mechanical properties driven by the SCCO2 phase transition are linked to the observed permeability reduction. First, observed reductions in coal strength and stiffness after SCCO2 saturation indicate a significant weakening effect - SCCO2 acts as a strong plasticizer enabling rearrangement of the physical structure and adding molecular mobility. The softened coal responds to increased compressional deformation and cleat closure under the same effective stress, resulting in a net permeability reduction in the supercritical region countering any influences of permeability-enhancing microcrack formation. Second, the SCCO2 permeability is further reduced by a large increase in sorption-induced swelling observed after the transition. Measured swelling strains indicate a > 90% increase in SCCO2 sorption-induced swelling relative to Langmuir response at 13 MPa. The enlarged SCCO2 adsorption capacity presumably results from the slightly polar nature of the SCCO2 dimer and the increased SCCO2 density. Permeability reduction due to plasticization and increased swelling is shown to dominate over permeability increases driven by brittle damage.

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