Watching excitations diffuse and charges recombine at interfaces in organic photovoltaic materials

John B. Asbury, Larry W. Barbour, Ryan D. Pensack

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Photoinduced charge separation, excitation transport, and charge recombination at the interfaces of polymer blend organic photovoltaic materials are examined using ultrafast visible pump - infrared probe spectroscopy. Native vibrational modes of both the electron donating polymers and electron accepting fullerenes are independently probed as local vibrational reporters of charge transfer yielding detailed dynamical information with structural specificity. Following ultrafast excitation, charge transfer to fullerene molecules occurs over many time scales ranging from sub-100 femtoseconds to nanoseconds. The slower component occurs because excitations that are created throughout the polymer phase must diffuse toward the interfaces to affect charge separation giving rise to an induction period in the charge transfer dynamics. The induction period occurs in the charge transfer kinetics observed in both the donor and acceptor transient vibrational spectra. Charge recombination is found to be composition dependent and occurs on the few microseconds to millisecond time scales.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society - 235th National Meeting, Abstracts of Scientific Papers
StatePublished - Dec 1 2008
Event235th National Meeting of the American Chemical Society, ACS 2008 - New Orleans, LA, United States
Duration: Apr 6 2008Apr 10 2008

Publication series

NameACS National Meeting Book of Abstracts
ISSN (Print)0065-7727

Other

Other235th National Meeting of the American Chemical Society, ACS 2008
CountryUnited States
CityNew Orleans, LA
Period4/6/084/10/08

Fingerprint

Charge transfer
Fullerenes
Polymers
Electrons
Vibrational spectra
Polymer blends
Pumps
Spectroscopy
Infrared radiation
Molecules
Kinetics
Chemical analysis

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Asbury, J. B., Barbour, L. W., & Pensack, R. D. (2008). Watching excitations diffuse and charges recombine at interfaces in organic photovoltaic materials. In American Chemical Society - 235th National Meeting, Abstracts of Scientific Papers (ACS National Meeting Book of Abstracts).
Asbury, John B. ; Barbour, Larry W. ; Pensack, Ryan D. / Watching excitations diffuse and charges recombine at interfaces in organic photovoltaic materials. American Chemical Society - 235th National Meeting, Abstracts of Scientific Papers. 2008. (ACS National Meeting Book of Abstracts).
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abstract = "Photoinduced charge separation, excitation transport, and charge recombination at the interfaces of polymer blend organic photovoltaic materials are examined using ultrafast visible pump - infrared probe spectroscopy. Native vibrational modes of both the electron donating polymers and electron accepting fullerenes are independently probed as local vibrational reporters of charge transfer yielding detailed dynamical information with structural specificity. Following ultrafast excitation, charge transfer to fullerene molecules occurs over many time scales ranging from sub-100 femtoseconds to nanoseconds. The slower component occurs because excitations that are created throughout the polymer phase must diffuse toward the interfaces to affect charge separation giving rise to an induction period in the charge transfer dynamics. The induction period occurs in the charge transfer kinetics observed in both the donor and acceptor transient vibrational spectra. Charge recombination is found to be composition dependent and occurs on the few microseconds to millisecond time scales.",
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Asbury, JB, Barbour, LW & Pensack, RD 2008, Watching excitations diffuse and charges recombine at interfaces in organic photovoltaic materials. in American Chemical Society - 235th National Meeting, Abstracts of Scientific Papers. ACS National Meeting Book of Abstracts, 235th National Meeting of the American Chemical Society, ACS 2008, New Orleans, LA, United States, 4/6/08.

Watching excitations diffuse and charges recombine at interfaces in organic photovoltaic materials. / Asbury, John B.; Barbour, Larry W.; Pensack, Ryan D.

American Chemical Society - 235th National Meeting, Abstracts of Scientific Papers. 2008. (ACS National Meeting Book of Abstracts).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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Asbury JB, Barbour LW, Pensack RD. Watching excitations diffuse and charges recombine at interfaces in organic photovoltaic materials. In American Chemical Society - 235th National Meeting, Abstracts of Scientific Papers. 2008. (ACS National Meeting Book of Abstracts).