Woodruffite: A new Mn oxide structure with 3 X 4 tunnels

Jeffrey E. Post, Peter J. Heaney, Christopher L. Cahill, Larry W. Finger

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

The mineral woodruffite, Zn2+x/2 (Mn4+1-x Mn3+x O2·yH2O, x ∼ 0.4 and y ∼ 0.7, is the first known example of a new type of Mn oxide characterized by large tunnels that measure 3 and 4 octahedra (6.9 × 9.2 Å on a side. These tunnels are rectangular in cross-section and are the largest of any yet reported in natural or synthetic Mn oxides. The thermal stability of woodruffite is comparable to that of todorokite and other large-tunnel Mn oxide phases, breaking down at ∼300 °C and eventually transforming to a spinel-type structure. The woodruffite structure may serve as a model for a new class of octahedral molecular sieves with enhanced capabilities as catalysts and selective cation-exchange agents.

Original languageEnglish (US)
Pages (from-to)1697-1702
Number of pages6
JournalAmerican Mineralogist
Volume88
Issue number11-12 PART 1
DOIs
StatePublished - 2003

All Science Journal Classification (ASJC) codes

  • Geophysics
  • Geochemistry and Petrology

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