ZnO-activated formation of phase pure perovskite Pb(In 1/2 Nb 1/2 )O 3 -Pb(Zn 1/3 Nb 2/3 )O 3 -PbTiO 3 powder

Michael J. Brova, Beecher H. Watson, Elizabeth R. Kupp, Mark A. Fanton, Richard J. Meyer, Gary L. Messing

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Abstract

This paper reports on the phase formation of perovskite Pb(In 1/2 Nb 1/2 )O 3 -Pb(Zn 1/3 Nb 2/3 )O 3 -PbTiO 3 (PIN-PZN-PT) powder when doped with 0.04 to 0.83 mol% ZnO. Air calcination of undoped powder mixtures for 4 hours at 800°C resulted in a mixture of Pb 2 Zn 0.29 Nb 1.71 O 6.565 pyrochlore, PIN-PZN-PT perovskite, and In 2 O 3 . ZnO dopant concentrations as low as 0.04 mol% increased the rate of perovskite formation and resulted in near phase pure perovskite powder of 0.5 µm particle size when heated at 800°C in air. In all cases PbTiO 3 and Pb(In 1/2 Nb 1/2 )O 3 formed prior to PIN-PZN-PT formation. ZnO doping promotes perovskite phase formation by increasing the reactivity of the intermediate pyrochlore phase by substituting Zn 2+ on Nb 5+ sites and forming oxygen vacancies when heated in air. Heating in high P O2 resulted in an incomplete reaction and a mixture of perovskite and pyrochlore whereas low P O2 resulted in phase separation into a mixture of rhombohedral perovskite, tetragonal perovskite, and pyrochlore. The P O2 sensitivity clearly shows that oxygen vacancies due to ZnO-doping are critical for synthesis of phase pure PIN-PZN-PT powder.

Original languageEnglish (US)
Pages (from-to)3932-3939
Number of pages8
JournalJournal of the American Ceramic Society
Volume102
Issue number7
DOIs
StatePublished - Jul 2019

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All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

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